National Journals
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Item TANNERY WASTEWATER REMEDIATION COMPETENCE OF METAL TOLERANT BACTERIA AND FUNGI UNDER THE INFLUENCE OF CHEMICALLY MODIFIED WATER HYACINTH BIOCHAR: AN IN VITRO EVALUATION(Springer Link, 2023-11-22) Kandasamy, Gajendiran; Ying, Ma; Sabariswaran, Kandasamy; Amal Abdullah, A. Sabour; Maha, Alshiekheid; Arivalagan, Pugazhendhi; Mathiyazhagan, NarayananThis study was trying to find a sustainable approach to remediate the tannery wastewater by various treatments sets (set-I to set-VIII: consists of KOH modified biochar, Bacillus cereus, and Aspergillus flavus biomass), and treatment successfulness was determined by phytotoxicity and cytotoxicity studies on potential Vigna unguiculata seedlings and Artemia franciscana larvae, respectively. Three tannery wastewater samples were collected from 3 sites (I, II, and III); among them, the physicochemical properties of site I were beyond the permissible limits containing more volume of harmful heavy metals such as Cr, Cd, Pb, As, Co, Cu, Fe, Zn, and Mn than other sample. The test B. cereus and A. flavus showed remarkable metal tolerance to heavy metals such as Cr, Cd, Pb, As, Co, Cu, Fe, Zn, and Mn at 800 µg mL−1. The bioremediation study results stated that the KOH modified pre-synthesized and characterized water hyacinth biochar with the blend of B. cereus and A. flavus (treatment set-VII) biomass substantially reduced/removed (Cr, Cd, Pd, As, Co, Cu, Fe, Zn, and Mn as 54.75%, 49.52%, 30.49%, 17.53%, 29.07%, 14.75%, 5%, 27.27%, and 9.2%, respectively) the heavy metals from the tannery wastewater. The treatment effectiveness was determined by phytotoxicity and cytotoxicity studies on V. unguiculata seedlings and A. franciscana larvae, respectively. Among various treatment sets, the set-VII demonstrated absence of phytotoxicity and cytotoxicity on V. unguiculata seedlings and A. franciscana larvae, respectively. This clearly shows that the KOH modified biochar with B. cereus and A. flavus biomass can be used to manage and treat tannery wastewater in a sustainable manner.Item A REVIEW ON LOW TEMPERATURE COMBUSTION ENGINES: PERFORMANCE, COMBUSTION AND EMISSION CHARACTERISTICS(Elsevier, 2019-12) Krishnamoorthi, M; Malayalamurthi, R; Zhixia, He; Sabariswaran, KandasamyLow temperature combustion (LTC) is a recent engine technology that can reduce the oxides of nitrogen (NOx) and soot emissions simultaneously while maintaining higher thermal efficiency. The present review work investigates the performance, emission and combustion characteristics of LTC mode engines. Partially premixed LTC (PPLTC), homogeneous charge compression ignition (HCCI), premixed charge compression ignition (PCCI) and reactivity controlled compression ignition (RCCI) modes are researched under LTC mode. In recent decades, different engine strategies have been employed to reduce exhaust emissions and to enhance thermal efficiency. Exhaust gas recirculation, variable valve timing (VVT), advanced fuel injection technologies are adapted to achieve LTC mode in internal combustion (IC) engines to get improved outcomes. This review highlights the properties of fuels, fuel supply systems, valve actuation mechanisms, engine operating conditions and its effects on the engine characteristics. This review provides a perspective plan to the researchers for enhancing the performance, emission and combustion behavior of an engine by using LTC mode with lower NOx and soot emissions. Among LTC mode engines, RCCI mode engine operates well in 60% load, 60% premixed ratio, 35:1 air-fuel ratio and 56% brake thermal efficiency within the combustion phasing control.Item IMPROVEMENT OF EMISSION REDUCTION IN NANO ADDITIVE SIMAROUBA GLAUCA BIODIESEL BLENDS(Taylor & Francis Online, 2018-06-26) Sabariswaran, Kandasamy; Selvakumar, SundararajIn this paper discussed about the emission profile from nano additive blended biodiesel. It is observed that minimum carbon dioxide was emitted in the presence of zinc oxide blends when compared to B20 and diesel. The hydrocarbon emission for the diesel and B20 was higher than that of the B20ZnO50 and B20ZnO100 blended fuels. The higher oxide of nitrogen emissions was observed with the B20ZnO50 and B20ZnO100 blended fuels at all engine loads when compared to B20 and diesel.Item DEVELOPMENT OF PORTABLE COLORIMETER FOR ON-SITE DETERMINATION OF WATER QUALITY IN AQUACULTURE(Pigment & Resin Technology, 2022-05-25) Kesavan, Devarayan; Madhan, Kathavarayan; Anand, Theivasigamani; Monikandon, Sukumaran; Sabariswaran, KandasamyThis study aims to describe the development of a battery-operated portable colorimeter for on-site determination of water quality in aquaculture.A simple and economical colorimeter is built using light sources of different wavelength and a light-dependent resistor combined with an electrical circuit. The whole system was fabricated as to fit into the pocket or palm for easy handling. The developed portable colorimeter was calibrated for estimation of nitrite. Further, the performance of developed portable colorimeters was compared with the commercially available colorimeter.Three colorimeters with different light sources were developed and calibrated for determination of nitrite in water. Among them, colorimeter with yellow light source exhibited higher potential for determination of nitrite in the range of 0.5–3.5 ppm. Further, the results of the developed colorimeter are comparable with the commercial colorimeter.The portable colorimeter developed in this study exhibits potential for determination of nitrite in aquaculture. Determination of nitrite at low concentrations is important for assessing the quality of culture as well as wastewater in aquaculture industry. The accuracy, portable nature, economy and simple operation of these portable colorimeters offer opportunity for on-site determination of water quality parameters in aquaculture.Item A REVIEW ON HYDROTHERMAL LIQUEFACTION OF ALGAL BIOMASS ON PROCESS PARAMETERS, PURIFICATION AND APPLICATIONS(Elsevier, 2022-04-01) Sathish Raam, Ravichandran; Chitra Devi, Venkatachalam; Mothil, Sengottian; Sarath, Sekar; Sabariswaran, Kandasamy; Kesav Prasath, Ramasamy Subramanian; Kirubakaran, Purushothaman; Aravindan Lavanya, Chandrasekaran; Mathiyazhagan, NarayananAlgae, a potential biomass feedstock with a faster growth rate and capability of greenhouse gas absorption, mitigates the limitations of the first- and second-generation feedstock in bio-oil production. hydrothermal liquefaction (HTL) is known to be an active method capable of producing substantial energy resources. In HTL, biomass undergoes thermal depolymerization in the presence of water, at around 280 °C–350 °C following subcritical and near supercritical conditions to produce chemical compounds such as alkanes, nitrogenates, esters, phenolics, etc. The primary product, “Biocrude/Bio-oil” obtained from the reaction, is identified as the essential fuel source after processing and also as a distinct value-added chemical source, along with biochar and biogas as co-products. This review outlines a range of routes available for thermochemical conversion of the algal biomass. It also provides a better understanding of the reaction mechanism like depolymerization, decomposition, and re-polymerization, operating conditions like temperature, pressure, the quantity of catalyst required, and the solvent used in the process. The review also highlights the yield achieved by altering the aforementioned parameters, comparing and presenting them as a collective result.Item ANTIBIOFILM ACTIVITY OF BIOSURFACTANT PRODUCED BY A SPONGE-ASSOCIATED MARINE COBETIA SP. JCG-23(Springer Link, 2023-09-22) Govindarajan, Ganesan; Chandrasekar, Balu; Suganthi, Ganesan; Samuel Raj, Babu Arulmani; Sabariswaran, KandasamyMarine symbiotically associated microbes play a vital role and are an excellent source of natural compounds that exert wide biological activities. In this study, we have reported on the identification, characterization, phylogenetic relationship, and anti-biofilm surface-active compound-producing abilities of marine invertebrate sponge-associated Cobetia sp. JCG-23. Among 24 isolates, a total of five strains (JCG2, JCG19, JCG20, JCG22, and JCG23) have active surface molecule producing potential on the emulsification index assay. Interestingly, the potential candidate JCG-23, produces biosurfactants with low surface tension (22 Nm-1) that exert anti-biofilm activity against Pseudomonas aeruginosa PAO1. The isolate was identified as genus Cobetia sp. JCG-23 with 99.1% sequence similarity to Cobetia crustatorum (EU909460) based on 16S rRNA gene sequence analysis. The large-scale production, purification, stability, and characterization of biosurfactant were carried out and its surface activity was determined using the oil drop method. Subsequent spectral analysis such as UV, FT-IR, and GC-MS analysis indicated that the purified biosurfactant was a hydroxyl fatty acid, namely octadecanoic acid (C18H36O2) with a molecular weight of 284 m/z. Furthermore, the effect of antibiofilm activity on the viability of Pseudomonas aeruginosa PAO1 by static ring tube and light and confocal laser scanning microscopy analysis revealed that the octadecanoic acid from Cobetia sp. JCG-23 has strong biofilm dismantle ability against Pseudomonas aeruginosa PAO1. Further characterization of the biosurfactant from the isolate Cobetia sp. JCG-23 can pave the way for developing novel bioactive agents targeting biofilm-forming pathogens on topical and medical devices.Item EFFICACY OF EISENIA BICYCLIS PHLOROTANNINS IN THE TREATMENT OF DIABETES AND REDUCING INFLAMMATION(Elsevier, 2023-04) Rathinam, Raja; Shanmugam, Hemaiswarya; Kulanthaiyesu, Arunkumar; N, Mathiyazhagan; Sabariswaran, Kandasamy; A, Arun; P, RamasamyCrude phlorotannins from Eisenia bicyclis (CPEb), a common perennial brown seaweed were screened for pharmacological activities such as anti-inflammatory, antioxidant, and antidiabetic effects. Crude Phlorotannins (CPEb) studied by FT-IR, LC-MS, UHPLC, and UV chromatography showed the occurrence of dieckol, 8, 8'-bieckol, fucofuroeckol, and the carotenoid, zeaxanthin (0.5 mg/kg). LPS, an inflammatory mediator, enhanced the production of cytokines such IL-1 (interleukin-1), IL-6 (interleukin-6), IL-8 (interleukin-8), IL-10 (interleukin-10), TNF-α (tumour necrosis factor-α), chemokine CXCL10, and NF-κB (nuclear factor kappa-light-chain-enhancer of activated B cells) in differentiated THP1 macrophage cells. On differentiated human monocytic cell line LPS-induced THP1 cells, CPEb was found to have anti-inflammatory effects by reducing the expression of IL-1, IL-6, IL-8 (1.2 fold), CXCL10, NF-κB, and TNF-α. CPEb promoted 2-NBDG absorption in differentiated C2C12 myotubes under both basal (16.08%) and insulin-stimulated (51.09%) conditions. CPEb increased IRS/AKT-dependent glucose absorption and also activates the AMPK pathway. Anti-α-glucosidase, anti-inflammatory and antioxidant activity of CPEb indicate their role in treating hyperglycemia by scavenging ROS and inflammatory responses.Item THE CURRENT STATE OF ALGAE IN WASTEWATER TREATMENT AND ENERGY CONVERSION: A CRITICAL REVIEW(Elsevier, 2023-06) Sabariswaran, Kandasamy; Mathiyazhagan, Narayanan; Rathinam, Raja; Kesavan, Devarayan; R, KavithaDue to the rapid expansion of the global economy and population, there aren't enough water resources accessible for direct human consumption. Therefore, water remediation will unavoidably take center stage on a worldwide platform. The development of microalgae can be supported by several types of wastewater (WW). They might be able to clean up pollutants from industry and urban effluents. Due to its low energy requirements, microalgae's capacity to survive in various environmental circumstances, and the potential to convert WW nutrients into high-value chemicals, microalgae-based wastewater treatment (WWT) has already received attention. Recent studies have reported using microalgae to remove pharmaceutical compounds and pesticides from wastewater produced by industrial and agricultural processes and removing nutrients from wastewater from WWTs. As a result, utilizing microalgae for both wastewater treatment and biofuel production could be a cost-effective solution to these challenges. This review emphasizes recent developments in the production of microalgae for WW cleanup. Additionally, it highlights the current problems and opportunities in the emerging algae-based sector.Item MICROBIAL DEGRADATION AND TRANSFORMATION OF PPCPS IN AQUATIC ENVIRONMENT: A REVIEW(Pub Med, 2023-08) Mathiyazhagan, Narayanan; Sabariswaran, Kandasamy; Jintae, Lee; Selvaraj, BarathiThe Pharmaceuticals and Personal Care Products (PPCPs) presence at harmful levels has been identified in aquatic ecosystems all over the world. Currently, PPCPs are more common in aquatic regions and have been discovered to be extremely harmful to aquatic creatures. Waste-water treatment facilities are the primary cause of PPCPs pollution in aquatic systems due to their limited treatment as well as the following the release of PPCPs. The degree of PPCPs elimination is primarily determined by the method applied for the remediation. It must be addressed in an eco-friendly manner in order to significantly improve the environmental quality or, at the very least, to prevent the spread as well as effects of toxic pollutants. However, when compared to other methods, environmentally friendly strategies (biological methods) are less expensive and require less energy. Most biological methods under aerobic conditions have been shown to degrade PPCPs effectively. Furthermore, the scientific literature indicates that with the exception of a few extremely hydrophobic substances, biological degradation by microbes is the primary process for the majority of PPCPs compounds. Hence, this review discusses about the optimistic role of microbe concerned in the degradation or transformation of PPCPs into non/less toxic form in the polluted environment. Accordingly, more number of microbial strains has been implicated in the biodegradation/transformation of harmful PPCPs through a process termed as bioremediation and their limitations.