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    QUANTUM CHEMICAL STUDY ON THE CORROSION INHIBITION PROPERTY OF SOME HETEROCYCLIC AZOLE DERIVATIVES
    (Oriental Journal of Chemistry, 2015-08-20) Anusuya, N; Sounthari, P; Saranya, J; Parameswari, K; Chitra, S
    Quantum chemical calculations based on density functional theory (DFT) method were performed on heterocyclic azole derivatives as corrosion inhibitors for mild steel in acid media to investigate the relationship between molecular structure of the inhibitors and the corresponding inhibition efficiencies (%). Quantum chemical parameters most relevant to their potential action as corrosion inhibitors have been calculated in the non-protonated and protonated forms in aqueous phase for comparison. Results obtained in this study indicate thatin acidic media, both the protonated and non-protonated forms of the azoles represent the better actual experimental situation.
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    ADSORPTION OF REACTIVE BLUE 171 FROM AQUEOUS SOLUTION USING LOW COST ACTIVATED CARBON PREPARED FROM AGRICULTURAL SOLID WASTE: ALBIZIA AMARA
    (Applied Science Innovations Pvt. Ltd., India, 2015-08-25) Anitha, K; Syed Shabudeen, P S; Karthikeyan, S; Aruna devi, N
    The adsorption of Reactive Blue 171 (Reactive Dye) from aqueous solution using activated carbon prepared from Albizia amara pod shell waste as an adsorbent have been carried out. The experimental adsorption data fitted reasonably well to Langmuir and Freundlich adsorption isotherms. Kinetic parameters as a function of Initial dye concentration have been calculated and the kinetic data were substituted in Pseudo First Order, Elovich and Pseudo Second order equations. A probable explanation is offered to account for the results of kinetic study. The thermodynamic parameter enthalpy change (∆H) suggests the exothermic nature of absorption of Reactive Blue 171 onto activated Albizia amara pod shell waste carbon.